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《中国科学:材料科学》2023年第2期

中国科学材料 中国科学材料 2023-02-01


Cover Story 

Lithium-sulfur batteries have been regarded as one of the next-generation high-energy density storage devices. However, the shuttle effect of polysulfide is one of the notable challenges for the practical use of lithium-sulfur batteries, especially in the high-polarity electrolytes. Zhao and coworkers demonstrate a proof-of-concept study to address this issue by constructing a two-phase electrolyte that is composed of a high-polarity electrolyte and a low-polarity electrolyte. The low-polarity electrolyte not only has good compatibility and superwettability to Li metal, but also shows the block effect of polysulfide in the two-phase electrolyte. Such unique twophase electrolytes can substantially improve the Coulombic efficiency and cyclic stability of lithium-sulfur batteries (see the article on page 505).


REVIEW

Recent advances in ZrO2 nanofibers: From structural design to emerging applications

ZrO2纳米纤维的最新进展: 从结构设计到新兴应用

Zhen Xu, Fei Wang, Xia Yin, Longdi Cheng, Jianyong Yu (俞建勇), Yitao Liu (刘一涛), Bin Ding

Sci China Mater, 2023, 66(2): 421–440



REVIEW

Recent progress of integrating MOFs into printed devices and their applications

金属有机框架集成到打印器件的最新进展及其应用

Hui Yang, Huijie Zhou, Guangxun Zhang, Xiaotian Guo, Huan Pang (庞欢)

Sci China Mater, 2023, 66(2): 441–469



REVIEW

Peptide-based porous materials and their applications

肽基多孔材料及其应用

Yuefei Wang (王跃飞), Jiwei Min, Hao Wei, Jiayu Liu, Yaoyu Liang, Rongxin Su, Gong Zhang, Wei Zhang, Yuefei Wang (王跃飞), Wei Qi (齐崴)

Sci China Mater, 2023, 66(2): 470–484



ARTICLE

Solution microcrystal enables a high-quality CsPbIBr2 film to minimize intragranular charge recombination for air-stable, carbon-based photovoltaics

溶液微晶提升全无机CsPbIBr2钙钛矿的薄膜质量并减小碳基光伏器件内部载流子复合

Furi Yan, Jialong Duan (段加龙), Qiyao Guo, Qiaoyu Zhang, Xiya Yang, Peizhi Yang (杨培志), Qunwei Tang (唐群委)

Sci China Mater, 2023, 66(2): 485–492



ARTICLE

In-situ processing nano-porous silicon into 3D conductive structure as high-capacity anode for lithium-ion batteries

锂离子电池用具有三维导电结构的纳米多孔硅高容量负极材料的原位加工

Jingjing Ma, Huan Zhang, Runqiang Liu, Wanqing Zhang, Shixing Han, Jin Han, Guangri Xu (许光日), Linsen Li, Yu-Shi He (何雨石), Zi-Feng Ma

Sci China Mater, 2023, 66(2): 493–504



ARTICLE

Inhibition of polysulfide shuttling in high-polarity electrolytes via liquid/quasi-solid interface in lithium-sulfur batteries

液态/准固态界面抑制锂硫电池中多硫化物在高极性电解质中的穿梭

Zhijie Guo, Xiaosheng Song, Xiaobing Wang, Chenxiao Wang, Xuhui An, Xiao Liu, Wenhao Wu, Tengfei Bian, Yong Zhao (赵勇)

Sci China Mater, 2023, 66(2): 505–512



ARTICLE

Bulk and interface-strengthened Li7P2.9Sb0.1S10.65O0.15I0.2 electrolyte via dual-source doping for all-solid-state lithium-sulfur batteries

通过双掺杂增强Li7P2.9Sb0.1S10.65O0.15I0.2电解质用于高性能全固态锂硫电池

Bo-Sheng Zhao, Peng Chen (陈鹏), Xue-Ping Gao (高学平)

Sci China Mater, 2023, 66(2): 513–521



ARTICLE

Three-dimensional hierarchical composite polymer electrolyte with enhanced interfacial compatibility for all-solid-state lithium metal batteries

三维分级复合固态电解质用于增强全固态锂金属电池界面相容性

Mengjun Wu, Jiangping Song, Xinxin Zhu, Hui Zhan, Tian Tian, Rui Wang, Jiaheng Lei, Haolin Tang (唐浩林)

Sci China Mater, 2023, 66(2): 522–530



ARTICLE

Selection of Cu2+ for intercalation from the electronegativity perspective: Improving the cycle stability and rate performance of δ-MnO2 cathode material for aqueous zinc-ion batteries

从电负性角度选择Cu2+插层: 提高水系锌离子电池δ-MnO2正极材料的循环稳定性和倍率性能

Zhenhua Liu, Yanpeng Liu, Yanan Zhang, Xiaoli Liu, De Yan (闫德), Juanjuan Huang (黄娟娟), Shanglong Peng (彭尚龙)

Sci China Mater, 2023, 66(2): 531–540



ARTICLE

Molecular engineering toward sustainable development of multiple-doped hierarchical porous carbons for superior zinc ion storage

分子工程化可持续制备多元素掺杂的分级多孔碳材料用于高性能锌离子存储

Mingquan Liu, Feng Wu, Xin Feng, Yahui Wang, Lumin Zheng, Xin Li, Ying Li, Yuteng Gong, Ying Bai (白莹), Chuan Wu (吴川)

Sci China Mater, 2023, 66(2): 541–555



ARTICLE

Anchoring high-mass iodine to nanoporous carbon with large-volume micropores and rich pyridine-N sites for high-energy-density and long-life Zn-I2 aqueous battery

大体积微孔和富吡啶氮掺杂的纳米多孔碳高效吸附碘用于高能量密度和长寿命Zn-I2水电池

Zongshuai Gong, Chunlai Song, Chong Bai, Xiaomeng Zhao, Zhiqiang Luo, Gaocan Qi, Xizheng Liu, Cheng Wang, Yueqin Duan (段月琴), Zhihao Yuan (袁志好)

Sci China Mater, 2023, 66(2): 556–566



ARTICLE

A NiCo bimetallic hydroxide electrode-based flexible Ni//Zn battery with smart electrochromic function for visually monitoring battery residual electricity

具有智能电致变色功能的镍钴双金属氢氧化物电极基柔性镍锌电池用于可视化监测剩余电量

Xiaoyang Xuan, Min Qian (钱敏), Likun Pan (潘丽坤), Ting Lu, Yang Gao, Yueping Niu, Shangqing Gong (龚尚庆)

Sci China Mater, 2023, 66(2): 567–576



ARTICLE

Bimetallic electron-induced phase transformation of CoNi LDH-GO for high oxygen evolution and supercapacitor performance

双金属电子诱导CoNi LDH-GO相变以提升其析氧和超级电容器性能

Wenhua Zhao, Tingting Liu, Niandu Wu, Boye Zhou, Yuxiang Yan, Yongchun Ye, Jiangfeng Gong, Shaoguang Yang (杨绍光)

Sci China Mater, 2023, 66(2): 577–586



ARTICLE

Nano/micro dual-scale ordered carbon units via template heredity toward compact capacitive energy storage

模板遗传实现纳微双尺度有序化碳单元及其在紧凑电容储能中的应用

Yongfeng Bu, Qin Kang, Wenya Jiang, Renxing Shi, Yan Zhou, Tao Sun, Lianshan Sun, Hongyu Liang (梁红玉)

Sci China Mater, 2023, 66(2): 587–596



ARTICLE

Facile dynamic current deposition of high tensile gradient Cu foil with (110) preferred orientation

简便的变电流沉积法制备高强度(110)择优取向梯度铜箔

Wei Liu, Geng Li, Yuankun Wang, Zhimeng Hao, Yufeng Zhang, Zhenhua Yan (严振华), Qing Zhao, Jun Chen

Sci China Mater, 2023, 66(2): 597–602



ARTICLE

Manipulating interface built-in electric fields for efficient spatial charge separation in hematite-based photoanodes

氧化铁光阳极界面内建电场调控强化光生电荷空间分离

Lianlian Mao, Hao Deng, Mingtao Li, Shaohua Shen (沈少华)

Sci China Mater, 2023, 66(2): 603–613



ARTICLE

Improving WO3/SnO2 photoanode stability by inhibiting hydroxyl radicals with cobalt ions in strong acid

通过钴离子抑制羟基自由基提高WO3/SnO2光阳极在强酸中的稳定性

Xiaobing Shi, Qianbao Wu, Chunhua Cui (崔春华)

Sci China Mater, 2023, 66(2): 614–622



ARTICLE

Integrated molten and vapor condensation of polymeric carbon nitride photoelectrode towards efficient water splitting

用于高效水分解的聚合氮化碳光电极的熔体相与气相一体化沉积

Yuqing Wang, Wenping Si (司文平), Haotian Tan, Zhiqiang Xie, Liqun Wang, Lu Di, Ji Liang, Feng Hou (侯峰)

Sci China Mater, 2023, 66(2): 623–633



ARTICLE

Heterointerface engineered NiFe(OH)x/Ni3S2 electrocatalysts to overcome the scaling relationship for ultrahigh-current-density water oxidation

异质界面功能化NiFe(OH)x/Ni3S2电催化剂及其超高电流密度下的析氧性能

Jiahao Zhang, Qiucheng Xu, Jingyu Wang, Yanjie Hu (胡彦杰), Hao Jiang (江浩), Chunzhong Li

Sci China Mater, 2023, 66(2): 634–640



ARTICLE

Carbon nanotubes anchored onto hollow carbon for efficient oxygen reduction

碳纳米管锚定在中空碳上用于高效氧还原反应

Qiuhong Sun, Dandan Chen, Qi Huang, Shaoming Huang, Jinjie Qian (钱金杰)

Sci China Mater, 2023, 66(2): 641–650



ARTICLE

Catalytic membrane electrode with Co3O4 nanoarrays for simultaneous recovery of water and generation of hydrogen from wastewater

Co3O4纳米阵列电催化膜电极及其处理难降解废水耦合产氢性能研究

Zhaohui Yin, Kun Zhang, Na Ma, Xi Liu, Zhen Yin (尹振), Hong Wang, Xue Yang, Ye Wang, Xuetao Qin, Danyang Cheng, Yumei Zheng, Lili Wang, Jianxin Li (李建新), Zongwei Xu, Na Tang, Bowen Cheng, Dequan Xiao, Ding Ma (马丁)

Sci China Mater, 2023, 66(2): 651–663



ARTICLE

Ultralong-lived triplet excitons of room-temperature phosphorescent carbon dots located on g-C3N4 to boost photocatalysis

利用室温磷光碳点提供的超长寿命三重态激子促进石墨相氮化碳的光催化性能

Xiaoyu Fang, Yanqun Tang, Yu-Juan Ma, Guowei Xiao, Pengyan Li, Dongpeng Yan (闫东鹏) 

Sci China Mater, 2023, 66(2): 664–671



ARTICLE

Atomically dispersed scandium Lewis acid sites on carbon nitride for efficient photocatalytic hydrogen peroxide production

原子分散的钪路易斯酸位点修饰氮化碳用于高效光催化合成过氧化氢

Shuang Yao, Ting Tang, Yongli Shen, Fan Yang (杨帆), Changhua An (安长华)

Sci China Mater, 2023, 66(2): 672–678



ARTICLE

Rhodium decorated stable platinum nickel nanowires for effective ethanol oxidation reaction

铑修饰的铂镍纳米线用于高效乙醇氧化反应

Qian Wang, Runxi Zhu, Peilin Deng (邓培林), Jing Li, Wei Huang, Qi Chen, Ya-Qiong Su (苏亚琼), Chunman Jia, Zhongxin Liu, Zhenye Kang (康振烨), Yijun Shen, Xinlong Tian (田新龙)

Sci China Mater, 2023, 66(2): 679–685



ARTICLE

Multidimensional synergy-induced high piezoelectricity and reliability KNN piezoceramics for high-frequency ultrasonic transducers

多维协同效应诱导的高压电性及可靠性的KNN压电陶瓷应用于高频超声换能器

Ruichen Li, Yushun Zeng, Xi-xi Sun, Chongyang Li, Runze Li, Ting Zheng, Laiming Jiang (蒋来明), Jiagang Wu (吴家刚)

Sci China Mater, 2023, 66(2): 686–695



ARTICLE

Entropy engineering enhances the thermoelectric performance and microhardness of (GeTe)1-x(AgSb0.5Bi0.5Te2)x

熵工程提高(GeTe)x(AgSb0.5Bi0.5Te2)1-x 的热电性能和显微硬度

Jinxuan Zhong, Gege Liang, Jiahui Cheng, Weiqin Ao, Chaohua Zhang, Junqin Li, Fusheng Liu, Shengnan Zhang (张胜楠), Lipeng Hu (胡利鹏)

Sci China Mater, 2023, 66(2): 696–706



ARTICLE

Rational design of stretchable and highly aligned organic/inorganic hybrid nanofiber films for multidirectional strain sensors and solar-driven thermoelectrics

可拉伸和高取向有机/无机复合纳米纤维膜用于多方向应变传感器和光驱动热电器

Liming Wang, Xinyang He, Yunna Hao, Maorong Zheng, Rongwu Wang (王荣武), Jianyong Yu, Xiaohong Qin (覃小红)

Sci China Mater, 2023, 66(2): 707–715



ARTICLE

Self-powered photodetectors based on CsPbBr3 quantum dots/organic semiconductors/SnO2 heterojunction for weak light detection

基于CsPbBr3量子点/有机半导体/SnO2异质结的自供电型探测器用于弱光检测

Ben Yang, Pu Guo, Dandan Hao, Yan Wang, Li Li, Shilei Dai (代世磊), Jia Huang (黄佳)

Sci China Mater, 2023, 66(2): 716–723



ARTICLE

Hybrid perovskite X-ray detectors with enhanced radioluminescence via thermally activated delayed fluorescence

热激活延迟荧光增强型钙钛矿闪烁体及其X射线探测器

Yalun Xu, Ao Ying, Jiali Peng, Fang Yao, Ruiming Li, Yao Tan, Shaolong Gong (龚少龙), Qianqian Lin (林乾乾)

Sci China Mater, 2023, 66(2): 724–732



ARTICLE

Directed self-assembly of organic crystals into chip-like heterostructures for signal processing

通过有机晶体定向自组装形成的用于信号处理的芯片状异质结构

Chao-Fei Xu, Wan-Ying Yang, Qiang Lv, Xue-Dong Wang (王雪东), Liang-Sheng Liao (廖良生)

Sci China Mater, 2023, 66(2): 733–739



ARTICLE

Ternary AGa5S8 (A = K, Rb, Cs): Promising infrared nonlinear optical materials rationally realized by “one-for-multiple substitution” strategy

三元AGa5S8 (A = K, Rb, Cs): 通过“一替多取代”策略制备的红外非线性光学材料

Wen-Fa Chen, Xiao-Ming Jiang, Shao-Min Pei, Ming-Shu Zhang, Bin-Wen Liu (刘彬文), Guo-Cong Guo (郭国聪)

Sci China Mater, 2023, 66(2): 740–747



ARTICLE

Unintentional doping effect in Si-doped MOCVD β-Ga2O3 films: Shallow donor states

硅掺杂MOCVD氧化镓中的非故意掺杂效应:浅施主态

Xueqiang Xiang, Li-Heng Li, Chen Chen, Guangwei Xu (徐光伟), Fangzhou Liang, Pengju Tan, Xuanze Zhou, Weibing Hao, Xiaolong Zhao, Haiding Sun, Kan-Hao Xue, Nan Gao (高南), Shibing Long

Sci China Mater, 2023, 66(2): 748–755



ARTICLE

Wafer-scale single-crystalline β-Ga2O3 thin film on SiC substrate by ion-cutting technique with hydrophilic wafer bonding at elevated temperatures

高温亲水性键合结合离子束剥离技术制备晶圆级β-Ga2O3/SiC异质集成材料

Zhenghao Shen, Wenhui Xu, Yang Chen, Jiajie Lin, Yuhuan Xie, Kai Huang, Tiangui You (游天桂), Genquan Han (韩根全), Xin Ou (欧欣)

Sci China Mater, 2023, 66(2): 756–763



ARTICLE

Native drift and Mott nanochannel in layered V2O5 film for synaptic and nociceptive simulation

层状V2O5薄膜中本征漂移和Mott纳米通道用于突触和痛觉感受器模拟

Wuhong Xue (薛武红), Caihong Gao, Zheng Zhang, Tingting Han, Nan Hou, Wenhui Yin, Lei Shi, Xiaoling Wang, Gang Liu, Xiaohong Xu (许小红)

Sci China Mater, 2023, 66(2): 764–771



ARTICLE

A novel high-entropy alloy with an exceptional combination of soft magnetic properties and corrosion resistance

一种兼具优异软磁性能和耐腐蚀性能的高熵合金

Jiacheng Duan, Mingliang Wang, Rui Huang, Junwei Miao, Yiping Lu (卢一平), Tongmin Wang, Tingju Li

Sci China Mater, 2023, 66(2): 772–779



ARTICLE

A low-density high-entropy dual-phase alloy with hierarchical structure and exceptional specific yield strength

一种低密度耐高温高比强度多层次结构双相高熵合金

Yasong Li, Wei-Bing Liao (廖卫兵), Huaican Chen, Jamieson Brechtl, Wenli Song, Wen Yin, Zhanbing He, Peter K. Liaw, Yong Zhang (张勇)

Sci China Mater, 2023, 66(2): 780–792


ARTICLE

Natural aging of metallic glasses

金属玻璃的自然老化

Yilin Yao, Qing Du, Yihuan Cao, Yuan Wu (吴渊), Xianzhen Wang, Xiongjun Liu, Hui Wang, Suihe Jiang, Zhaoping Lu (吕昭平)

Sci China Mater, 2023, 66(2): 793–800



ARTICLE

Significant enhancement of transport JC in Cu/Ag-sheathed (Ba,K)Fe2As2 superconducting tapes by pre-composite technique

预复合包套技术制备的高性能(Ba,K)Fe2As2铁基超导带材

Wenchao Li, He Huang, Chen Guo, Chang Tu, Xinyuan Liu, Chao Yao, Xianping Zhang, Yanwei Ma (马衍伟)

Sci China Mater, 2023, 66(2): 801–810



ARTICLE

Schottky barrier heights and mechanism of charge transfer at metal-Bi2OS2 interfaces

金属-Bi2OS2界面肖特基势垒以及电荷转移机制研究

Xiaodong Zhang, Liping Feng (冯丽萍), Shichen Zhong, Yuanming Ye, Haixi Pan, Pengfei Liu, Xiaoqi Zheng, Huanyong Li, Mingyang Qu, Xitong Wang

Sci China Mater, 2023, 66(2): 811–818



ARTICLE

Transferable prediction of intermolecular coupling achieved by hierarchical material representation

创建层次化材料表象以实现分子间耦合的可迁移预测

Chong Li, Chao Liang, Yilimiranmu Rouzhahong, Biao Wang, Huashan Li (李华山)

Sci China Mater, 2023, 66(2): 819–826



ARTICLE

Platelet magnetic nanocarriers as MRI sensors to delineate vascular injury network and targeted pre-protection in ischemic stroke

血小板膜磁性纳米载体作为MR影像传感器用于缺血性脑卒中血管损伤网络的描绘及靶向预保护

Mingxi Li, Xiao Cheng, Zhe Chen, Zhonghua Ni, Ning Gu, Fang Yang (杨芳) 

Sci China Mater, 2023, 66(2): 827–835



HIGHLIGHT

An old kid in the block: 2D polymeric C60

Kian Ping Loh

Sci China Mater, 2023, 66(2): 836–836


HIGHLIGHT

Pit pairs in ginkgo seed shell guide the crack

Si-Ming Chen, Xiang-Sen Meng, Shu-Hong Yu (俞书宏)

Sci China Mater, 2023, 66(2): 837–838


2022年全12期文章目录(点击链接可查看各期目录)

《中国科学:材料科学》2022年第12期 专辑: 面向碳中和的能源转换《中国科学:材料科学》2022年第11期
《中国科学:材料科学》2022年第10期
《中国科学:材料科学》2022年第9期《中国科学:材料科学》2022年第8期 专辑: 柔性智能材料《中国科学:材料科学》2022年第7期《中国科学:材料科学》2022年第6期《中国科学:材料科学》2022年第5期《中国科学:材料科学》2022年第4期《中国科学:材料科学》2022年第3期《中国科学:材料科学》2022年第2期《中国科学:材料科学》2022年第1期
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